Asta y Yuno llegan al lugar donde se celebrará el examen de caballería y comenzarán con sus pruebas ante la atenta mirada de los nueve capitanes de las órdenes mágicas.

La presencia de plebeyos entre los caballeros mágicos es algo que pocos del grupo aceptan y la tensión se hace patente en la reunión. Cuando todos están dispuestos a enfrentarse, un grupo desconocido ataca la capital.

Finral ha preparado una cita grupal con tres chicas, pero debe escoger a dos de sus compañeros como acompañantes.

Yami enfrenta a Licht, líder de Ojo de la Noche Blanca, y parece derrotarlo, pero es entonces cuando aparecen personas incluso más peligrosas.

Los Toros Negros se enfrentan a los magos del Templo Submarino, aunque su líder parece haber subestimado en gran medida las capacidades del que dicen que es el peor gremio de Caballeros Mágicos.

Captain Charlotte of the Blue Rose Knights thinks back to her past, but not before she and Vanessa battle it out in more than one ill-advised contest.

Todos se unen para acabar con el diablo, y es que si no es con un enorme esfuerzo conjunto, no hay ninguna posibilidad de vencer.

Though Vangeance, the Captain of the Golden Dawn, had asked Langris to return to his duties as vice captain, he continues to distance himself from the squad. Yuno had suddenly moved up all the ranks at a decoration ceremony and Langris asks him to fight him. The rest of the squad seems shocked, but Yuno accepts Langris’ request and fights him and they have a fierce battle. But during their fight, Yuno seems to have some doubts with how Langris is fighting.

Due to Nacht's spell, the Devil who has been granting Asta power since the beginning has appeared physically. To master his Devil powers, Asta must battle and defeat his Devil, and force him to submit. But Asta has other plans... Meanwhile, Yuno, Noelle, and the others grow stronger in order to take their revenge against the Dark Triad.